单词 | detailed balance |
释义 | detailed balance The cancellation of the effect of one process by another process that operates at the same time with the opposite effect. An example of detailed balance is provided by a chemical reaction between two molecular species A and B, which results in the formation of the molecular species C and D. Detailed balance for this chemical reaction occurs if the rate at which the reaction A + B → C + D occurs is equal to the rate at which the reaction C + D → A + B occurs. The equilibrium state in thermodynamics is characterized by detailed balance. When there is detailed balance in a system, the self-organization far from equilibrium associated with nonequilibrium statistical mechanics cannot occur |
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