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单词 activity
释义 activity
1 Symbol a. A thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For example, in a reaction
A ? B + C
the true equilibrium constant is given by
K = aBaC/aA
where aA, aB, and aC are the activities of the components, which function as concentrations (or pressures) corrected for nonideal behaviour. Activity coefficients (symbol γ) are defined for gases by γ = a/p (where p is pressure) and for solutions by γ = aX (where X is the mole fraction). Thus, the equilibrium constant of a gas reaction has the form
KpBPBγCPCAPA
The equilibrium constant of a reaction in solution is
Kc = γBXBγCAXA
The activity coefficients thus act as correction factors for the pressures or concentrations. See fugacity.
2 Symbol A. The number of atoms of a radioactive substance that disintegrate per unit time. The specific activity (a) is the activity per unit mass of a pure radioisotope. See radiation units.
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更新时间:2025/12/25 0:14:55